Cu (II) and ammonium adsorption from dairy cattle breeding sewage by phosphorus-modified dairy cow manure hydrochar
Keywords:
dairy manure, hydrochar, sewage, adsorption, competitive adsorptionAbstract
To realize the synergistic treatment of dairy cow manure solids and dairy cattle breeding sewage, this study produced phosphorus-modified hydrochar by dairy cow manure solids impregnated with potassium phosphate (K3PO4). And then, the adsorption characteristics of Cu (II) and ammonium (NH4+) in dairy cattle breeding sewage under different dosages and adsorption time conditions of modified hydrochar were explored. The results show that the specific surface area and total pore volume of the hydrochar were increased by phosphorus-modified. The adsorption amount of hydrochar per unit-mass decreased with the increase in the dosage. With the increase in the dosage, the adsorption capacity of Cu (II) decreased from the initial 26.16 mg/g to 3.38 mg/g. The adsorption of Cu (II) and NH4+ in sewage by hydrochar was mainly chemical adsorption, which was mainly affected by chelation and ion exchange. This adsorption was more inclined to single-molecular layer adsorption. Both the pH values and the ionic strength influenced the competitive adsorption between Cu (II) and NH4+. The higher the pH value was, the greater the adsorption amount, and the stronger the adsorption capacity by hydrochar. Moreover, the increase in the ionic strength decreases the adsorption capacity of hydrochar. Keywords: dairy manure, hydrochar, sewage, adsorption, competitive adsorption DOI: 10.25165/j.ijabe.20221505.7640 Citation: Yang Z D, Tong M, He X Q, Han L J, Guo J B, Jing T J, et al. Cu (II) and ammonium adsorption from dairy cattle breeding sewage by phosphorus-modified dairy cow manure hydrochar. Int J Agric & Biol Eng, 2022; 15(5): 78–84.References
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[2] Zhang S Y, Hong R Y, Cao J P, Takarada T. Influence of manure types and pyrolysis conditions on the oxidation behavior of manure char. Bioresource Technology, 2009; 100(18): 4278–4283.
[3] Kong F K, Shao L, Yang S J, Luo X, Wang W, Ju X X, et al. Application of solid-liquid separation technology in manure water treatment and resource utilization of livestock and poultry breeding. Swine Industry Science, 2017; 34(4): 96–98. (in Chinese)
[4] Yang P Y. The performance of membrane bioreactor treating wastewater from dairy farm. Master dissertation. Beijing: Chinese Academy of Agricultural Sciences, 2019; 75p. (in Chinese)
[5] Herath A, Reid C, Perez F, et al. Biochar-supported polyaniline hybrid for aqueous chromium and nitrate adsorption. Journal of Environmental Management, 2021, 296: 113186. doi: 10.1016/j.jenvman.2021.113186.
[6] Liu Q. Preparation of coconut shell-sludge composite activated carbon and its study on the adsorption of Cr(VI) in simulated wastewater. Master dissertation. Chengdu: Southwest Petroleum University, 2018; 69p. (in Chinese)
[7] Niinipuu M, Latham K G, Boily J-F, Bergknut M, Jansson S. The impact of hydrocharization on the surface functionalities of wet waste materials for water treatment applications. Environmental Science and Pollution Research, 2020; 27(19): 24369–24379.
[8] Kaewtrakulchai N, Putta A, Pasee W, Fuangnawakij K, Panomsuwan G, Eiad-ua A. Magnetic carbon nanofibers from horse manure via hydrocharization for methylene blue adsorption. IOP Conference Series: Materials Science and Engineering, 2019; 540(1): 12006. doi: 10.1088/1757-899X/540/1/012006.
[9] Ma Q Y, Logan T J, Traina S J. Lead immobilization from aqueous-solutions and contaminated soils using phosphate rocks. Environmental Science & Technology, 1995; 29(4): 1118–1126.
[10] Wu H Y. Adsorption behavior of Pb(II) and phenol by activated carbon prepared by shaddock peel. Master dissertation. Taiyuan: Taiyuan University of Science and Technology, 2020; 72p. (in Chinese)
[11] Zhou S M, Han L J, Yang Z L, Ma Q L. Influence of hydrocharization
temperature on combustion characteristics of livestock and poultry manures. Transactions of the CSAE, 2017; 33(23): 233–240. (in Chinese)
[12] Yuan J. Preparation of sewage sludge hydrothermal charcoal and its removal effect on heavy metals in water. Master dissertation. Shanghai: Donghua University, 2019; 100p. (in Chinese)
[13] Yu J G. Hydrothermal modification of agricultural waste biomass charcoal and study of its adsorption performance. Master dissertation. Dalian: Dalian University of Technology, 2018; 71p. (in Chinese)
[14] Qiao N. Hydrocharization of corncob and pinenut shell and the adsorption performance of its product. Master dissertation. Dalian: Dalian University of Technology, 2015; 65p. (in Chinese)
[15] Sun Y Y. Co-transport simulation and model parameter analysis of heavy metals and ammonium nitrogen in the soil. Master dissertation. Qingdao: Qingdao University, 2013; 94p. (in Chinese)
[16] N.Wibowo, L.Setyadhi, D.Wibowo, J.Setiawan, S.Ismadji. Adsorption of benzene and toluene from aqueous solutions onto activated carbon and its acid and heat-treated forms: Influence of surface chemistry on adsorption. Journal of Hazardous Materials, 2007; 146(1-2): 237–242.
[17] Martins A C, Pezoti O, Cazetta A L, Bedin K C, Yamazaki D A S, Bandoch G F G, et al. Removal of tetracycline by naoh-activated carbon produced from macadamia nut shells: Kinetic and equilibrium studies. Chemical Engineering Journal, 2015; 260: 291–299.
[18] Zhang P Z, Zhang X X, Yuan X R, Xie R Y, Han L J. Characteristics, adsorption behaviors, Cu(II) adsorption mechanisms by cow manure biochar derived at various pyrolysis temperatures. Bioresource Technology, 2021; 331: 125013. doi: 10.1016/j.biortech.2021.125013.
[19] Chang M Y, Juang R S. Adsorption of tannic acid, humic acid, and dyes from water using the composite of chitosan and activated clay. Journal of Colloid and Interface Science, 2004, 278(1): 18–25.
[20] Cai J. The study of adsorption of cadmium in aqueous solution by phosphate-modified bamboo biochar. Master dissertation. Wuhan: Huazhong University of Science and Technology, 2018; 72p. (in Chinese)
[21] Han L J, Li Y L, Liu X, Han Y H. Review of biochar as adsorbent for aqueous heavy metal removal. Transactions of the CSAM, 2017; 48(11): 1–11. (in Chinese)
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[24] Jin K, Lu Q, Ma L J, Li H J, Shi Z J. Preparation of walnut shell carbon and its adsorption of ammonia-nitrogen wastewater. Biomass Chemical Engineering, 2021; 55(1): 63–69. (in Chinese)
[25] Rajabi H, Mosleh H M, Prakoso T, Ghaemi N, Mandal P, Lea-Langton A, et al. Competitive adsorption of multicomponent volatile organic compounds on biochar. Chemosphere, 2021; 283: 131288. doi: 10.1016/j.chemosphere.2021.131288.
[26] Karami H. Heavy metal removal from water by magnetite nanorods. Chemical Engineering Journal, 2013; 219: 209–216.
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Published
2022-11-01
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Yang, Z., Tong, M., He, X., Han, L., Guo, J., Jing, T., … Shi, C. (2022). Cu (II) and ammonium adsorption from dairy cattle breeding sewage by phosphorus-modified dairy cow manure hydrochar. International Journal of Agricultural and Biological Engineering, 15(5), 78–84. Retrieved from https://ijabe.migration.pkpps03.publicknowledgeproject.org/index.php/ijabe/article/view/7640
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