Analytical study on pyrolyzed products of Desmodesmus sp. cultivated in BG11
Keywords:
Desmodesmus sp., microalgae, pyrolyzed products, pyrolysis temperature, bio-oilAbstract
Abstract: Pyrolysis-Gas Chromatography-Mass Spectrometry (Py-GC/MS) was adopted to determine the changes in component of BG11-cultivated Desmodesmus sp. (BG11/8-10) pyrolyzed products at different temperature (300°C-800°C). The results of analysis on a series of total ions chromatogram (TIC) showed that pyrolyzed products of BG11/8-10 at different temperature mainly included aliphatic hydrocarbons, nitrogen compounds, aromatic hydrocarbons, fatty acids, ketones, alcohols, aldehydes and furan compounds. Compared to the bio-oil (42.36%) generated by pyrolysis at 700°C, the relative content of bio-oil generated at 800°C was the highest up to 56.96%. However, higher temperature could easily cause the generation of large quantities of such pollutants as nitrogen compounds and polycyclic aromatic hydrocarbons (PAHs). Therefore, based on lower pollutant discharge and higher bio-oil yield, the optimal pyrolysis temperature of BG11/8-10 was around 700°C. Keywords: Desmodesmus sp., microalgae, pyrolyzed products, pyrolysis temperature, bio-oil DOI: 10.3965/j.ijabe.20171003.2942 Citation: Li G, Ji F, Xiang S, Zhou Y G, Jiang M M, Huang Z G. Analytical study on pyrolyzed products of Desmodesmus sp. cultivated in BG11. Int J Agric & Biol Eng, 2017; 10(3): 218–226.References
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[4] Raveendran K, Ganesh A. Heating value of biomass and biomass pyrolyzed products. Fuel, 1996; 75: 1715–1720.
[5] Maddi B, Viamajala S, Varanasi S. Comparative study of pyrolysis of algal biomass from natural lake blooms with lignocellulosic biomass. Bioresour. Technol., 2011; 102(23): 11018–11026.
[6] Ross A B, Anastasakis K, Kubacki M, Jones J M. Investigation of the pyrolysis behaviour of brown algae before and after pre-treatment using PY-GC/MS and TGA. J. Anal. Appl. Pyrolysis, 2009; 85(1): 3–10.
[7] Zhang M, Resende F L P, Moutsoglou A. Pyrolysis of lignin extracted from prairie cordgrass, aspen, and Kraft lignin by Py-GC/MS and TGA/FTIR. J. Anal. Appl. Pyrolysis, 2012; 98: 65–71.
[8] Thangalazhy-Gopakumar S, Adhikari S, Chattanathan S A, Gupta R B. Catalytic pyrolysis of green algae for hydrocarbon production using H+ZSM-5 catalyst. Bioresour. Technol., 2012; 118: 150–157.
[9] Du Z, Ma X, Li Y, Chen P, Liu Y, Lin X. Production of aromatic hydrocarbons by catalytic pyrolysis of microalgae with zeolites: Catalyst screening in a pyroprobe. Bioresour. Technol., 2013; 139: 397–401.
[10] Li G, Zhou Y G, Ji F, Liu Y, Adhikari B, Li T. Yield and characteristics of pyrolyzed products obtained from Schizochytrium Limacinum under different temperature regimes. Energies, 2013; 6(7): 3339–3352.
[11] Bligh E, Dyer W J. A rapid method of total lipid extraction and purification. Can. J. Biochem. Physiol., 1959; 37(8): 911–917.
[12] Rao Q, Labuza T P. Effect of moisture content on selected physicochemical properties of two commercial hen egg white powers. Food Chem., 2012; 132(1): 373–384.
[13] Mahinpey N, Murugan P, Mani T, Raina R. Analysis of bio-oil, biogas, and biochar from pressurized pyrolysis of wheat straw using a tubular reactor. Energy Fuels, 2009; 23(5): 2736–2742.
[14] Friedl A, Padouvas E, Rotter H, Varmuza K. Prediction of heating values of biomass fuel from elemental composition. Anal. Chim. Acta, 2005; 544(1): 191–198.
[15] Harman-Ware A E, Morgan T, Wilson M, Crocker M, Zhang J, Liu K. Microalgae as a renewable fuel source: Fast pyrolysis of Scenedesmus sp. Renew. Energy, 2013; 60: 625–632.
[16] Li R, Zhong Z, Jin B, Zheng A. Selection of temperature for bio-oil production from pyrolysis of algae from lake blooms. Energy Fuels, 2012; 26(5): 2996–3002.
[17] Du Z, Li Y, Wang X, Wan Y, Chen Q, Wang C, et al. Microwave-assisted pyrolysis of microalgae for biofuel production. Bioresour. Technol., 2011; 102(7): 4890–4896.
[18] Maggi R, Delmon B. Characterization and upgrading of bio-oils produced by rapid thermal processing. Biomass Bioenergy, 1994; 7(1): 245–249.
[19] Miao X, Wu Q. High yield bio-oil production from fast pyrolysis by metabolic controlling of Chlorella protothecoides. J. Biotechnol., 2004; 110(1): 85–93.
[20] Duan P, Savage P E. Catalytic treatment of crude algal bio-oil in supercritical water: optimization studies. Energy Environ. Sci., 2011; 4(4): 1447–1456.
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Published
2017-05-31
How to Cite
Gang, L., Fang, J., Shunan, X., Yuguang, Z., Mengmeng, J., & Zhigang, H. (2017). Analytical study on pyrolyzed products of Desmodesmus sp. cultivated in BG11. International Journal of Agricultural and Biological Engineering, 10(3), 218–226. Retrieved from https://ijabe.migration.pkpps03.publicknowledgeproject.org/index.php/ijabe/article/view/2942
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Renewable Energy and Material Systems
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